Questions with detailed step by step solutions from Chemical Thermodynamics

Topics covered under Chemical Thermodynamics
Fundamentals of thermodynamics: System and surroundings, extensive and intensive properties, state functions, types of processes. First law of thermodynamics: Concept of work, heat internal energy and enthalpy, heat capacity, molar heat capacity; Hess’s law of constant heat summation; Enthalpies of bond dissociation, combustion, formation, atomization, sublimation, phase transition, hydration, ionization and solution. Second law of thermodynamics: Spontaneity of processes; ΔS of the universe and ΔG of the system as criteria for spontaneity, ΔGo (Standard Gibbs energy change) and equilibrium constant.
Some Basic Terms and Concepts
Heat Capacity, Specific Heat Capacity and Molar Heat Capacity
Measurement of Delta U and Delta H - Calorimetry
Different Types of Heats/Enthalpies of Reaction
Spontaneous and Non-Spontaneous Process
Entropy and Gibbs Free Energy
Standard Free Energy and Third Law of Thermodynamics
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